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Mining was unmechanized and labor-intensive, with pickmen freeing the ore from the rock, and mine-boys or carusi carrying baskets of ore to the surface, often through a mile or more of tunnels. Once the ore was at the surface, it was reduced and extracted in smelting ovens.

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Apart from coal, opportunities in Poland and the wider Central European region exist in mineral and metal mining and processing operations, including Copper, Zinc, Cobalt, Sulphur and Lithium. The varied mineral deposits are concentrated mainly in the southern regions and adjacent areas.

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Copper ore is mined only in the Legnica-Glogow Copper District by KGHM Polska Miedz SA, Poland's sole producer of copper from primary materials. In 2000, 27 million tons of ore were mined there, yielding about 480,000 tons of copper.

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Sulfur mining takes place in countries such as Poland, Russia, Ukraine, United States and Turkmenistan. Ijen, a quiet but active volcano in East Java, Indonesia contains a one kilometer wide crater lake; a well known site of sulfur mining.

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